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Synergistic effects of antioxidant and silica on enhancing
In this work, the thermo-oxidative aging performance of antioxidant N-isopropyl-N′-phenyl-p-phenylenediamine (4010NA)/silica (SiO 2)/natural rubber (NR) composite was evaluated by the variations of mechanical properties and chemical structure after aging at 100 °C.Compared with 4010NA/carbon black (CB)/NR composite, there existed significant synergistic effects between 4010NA and SiO 2 on
occurring materials such as waxes, coal tar, creosote and many other products were used early on to “coat” rubber articles; providing the needed protection from oxidation. These protective coatings would be “scuffed” or “worn” off and the unprotected rubber would soon fail; resulting in the need to find a more permanent solution.
High-performance liquid chromatography of rubber
The HPLC method has also been applied to the determination of the antioxidant PBN contents in rubber samples used as the raw materials. Detection limits were 0.26, 0.14 and 0.41 mg/kg for CD, PBN and TMQ, respectively.